WEKO3
Item
A tricky water molecule coordinated to a verdazylradical-iron(II) complex: a multitechniqueapproach
https://aist.repo.nii.ac.jp/records/2001969
https://aist.repo.nii.ac.jp/records/2001969d88c3f62-06f0-4915-b718-f6a9d805cd2a
| Item type | Research Data (v9)(1) | |||||||||||||||
|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|---|
| PubDate | 2014-01-01 | |||||||||||||||
| Data name | ||||||||||||||||
| Title | A tricky water molecule coordinated to a verdazylradical-iron(II) complex: a multitechniqueapproach | |||||||||||||||
| Language | en | |||||||||||||||
| Description of data | ||||||||||||||||
| Description Type | Abstract | |||||||||||||||
| Description | In this paper, we extend this series to the iron(II) derivativessynthesized either in H2O leading to [Fe(vdCOO)2(H2O)2]2H2O(1) or inD2O leading to [Fe(vdCOO)2(D2O)2]2D2O (2). The crystalstructures of 1 and 2 are investigated by single-crystal X-raydiffraction at room temperature and at 90 K. In the complex, onecoordinated water molecule has a rather abnormal behavior.To tackle this phenomenon, we use a multi-technique approachrelying on the simultaneous analysis of X-ray crystallographicdata, 57Fe Mo¨ssbauer spectroscopy and solid state 2H-NMRspectroscopy. Moreover, the magnetic properties are investigatedby variable-temperature magnetic susceptibility measurementsbetween 300 K and 2 K. The exchange interactionparameters of the whole series of complexes (M = Fe, Co, Ni)are analyzed and discussed. | |||||||||||||||
| Language | en | |||||||||||||||
| Author (Creator) name |
Hajime Kamebuchi
× Hajime Kamebuchi
× 大久保 将史
× Atsushi Okazawa
× Masaya Enomoto
× Jun Harada
|
|||||||||||||||
| Access Rights | ||||||||||||||||
| Access Rights | open access | |||||||||||||||
| Access Rights URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||||||
| APC | ||||||||||||||||
| APC | Not required | |||||||||||||||
| Rights Holder | ||||||||||||||||
| Right Holder Name | Hajime Kamebuchi | |||||||||||||||
| Language | en | |||||||||||||||
| Publisher | ||||||||||||||||
| Publisher | ROYAL SOC CHEMISTRY | |||||||||||||||
| Language | en | |||||||||||||||
| Date | ||||||||||||||||
| Date | 2014-01-01 | |||||||||||||||
| Date Type | Issued | |||||||||||||||
| Language | ||||||||||||||||
| Language | eng | |||||||||||||||
| Resource Type | ||||||||||||||||
| Resource Type Identifier | http://purl.org/coar/resource_type/c_6501 | |||||||||||||||
| Resource Type | journal article | |||||||||||||||
| Identifier | ||||||||||||||||
| Identifier | 10.1039/C4CP00310A | |||||||||||||||
| Identifier Type | DOI | |||||||||||||||
| Relation | ||||||||||||||||
| Relation Type | isVersionOf | |||||||||||||||
| Identifier Type | URI | |||||||||||||||
| Related Identifier | http://pubs.rsc.org/en/Content/ArticleLanding/2014/CP/c4cp00310a#!divAbstract | |||||||||||||||
| Language | ja | |||||||||||||||
| Related Title | 関連 URI | |||||||||||||||
| Source Title | ||||||||||||||||
| Source Title | PHYSICAL CHEMISTRY CHEMICAL PHYSICS | |||||||||||||||
| Language | en | |||||||||||||||
| Volume Number | ||||||||||||||||
| Volume | 16 | |||||||||||||||
| Issue Number | ||||||||||||||||
| Issue | 19 | |||||||||||||||
| Page Start | ||||||||||||||||
| Start Page | 9086 | |||||||||||||||
| Page End | ||||||||||||||||
| End Page | 9095 | |||||||||||||||
