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Item
Highly Efficient Extraction of Rhodium(III) from Hydrochloric Acid Solution with Amide-Containing Tertiary Amine Compounds
https://aist.repo.nii.ac.jp/records/2001836
https://aist.repo.nii.ac.jp/records/2001836da22324d-9125-4824-95ea-0fa25bd66c38
| Item type | Research Data (v9)(1) | |||||||||||
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| PubDate | 2015-01-01 | |||||||||||
| Data name | ||||||||||||
| Title | Highly Efficient Extraction of Rhodium(III) from Hydrochloric Acid Solution with Amide-Containing Tertiary Amine Compounds | |||||||||||
| Language | en | |||||||||||
| Description of data | ||||||||||||
| Description Type | Abstract | |||||||||||
| Description | Extraction of Rh(III) from a HCl solution with N,N-disubstituted amide–containing tertiary amine (ACTA) compounds (N,N-di-n-hexyl(N-methyl-N-n-octyl-ethylamide)amine (MonoAA), N-n-hexyl-bis(N-methyl-N-n-octyl-ethylamide)amine (BisAA), and tris(N-methyl-N-n-octyl-ethylamide)amine (TrisAA)) was investigated. The ACTAs extract Rh(III) more efficiently than tri-n-octylamine (TOA), and the extraction efficiency increases with increasing number of amide groups: TrisAA > BisAA > MonoAA >> TOA. For all ACTAs, the predominant Rh(III) complex extracted from 2 M HCl is probably [{RhCl5(H2O)}∙(ACTA∙H)2]. The apparent basicity of the ACTAs and TOA varies in the opposite order from that observed for the Rh(III) extraction efficiency. Rh(III) can be readily back-extracted using 10 M HCl solution possessing a high selectivity over similarly loaded Pd(II) and Pt(IV). | |||||||||||
| Language | en | |||||||||||
| Author (Creator) name |
成田 弘一
× 成田 弘一
× 森作 員子
× 田中 幹也
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| Access Rights | ||||||||||||
| Access Rights | open access | |||||||||||
| Access Rights URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||
| APC | ||||||||||||
| APC | Not required | |||||||||||
| Rights Holder | ||||||||||||
| Right Holder Name | 成田 弘一 | |||||||||||
| Language | en | |||||||||||
| Publisher | ||||||||||||
| Publisher | TAYLOR & FRANCIS INC | |||||||||||
| Language | en | |||||||||||
| Date | ||||||||||||
| Date | 2015-01-01 | |||||||||||
| Date Type | Issued | |||||||||||
| Language | ||||||||||||
| Language | eng | |||||||||||
| Resource Type | ||||||||||||
| Resource Type Identifier | http://purl.org/coar/resource_type/c_6501 | |||||||||||
| Resource Type | journal article | |||||||||||
| Identifier | ||||||||||||
| Identifier | 10.1080/07366299.2015.1012883 | |||||||||||
| Identifier Type | DOI | |||||||||||
| Relation | ||||||||||||
| Relation Type | isVersionOf | |||||||||||
| Identifier Type | URI | |||||||||||
| Related Identifier | http://www.tandfonline.com/doi/abs/10.1080/07366299.2015.1012883?journalCode=lsei20 | |||||||||||
| Language | ja | |||||||||||
| Related Title | 関連 URI | |||||||||||
| Source Title | ||||||||||||
| Source Title | SOLVENT EXTRACTION AND ION EXCHANGE | |||||||||||
| Language | en | |||||||||||
| Page Start | ||||||||||||
| Start Page | 407 | |||||||||||
| Page End | ||||||||||||
| End Page | 417 | |||||||||||
