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Item
Dynamic Design of Cross Linked Soft Material driven by Iron Complex
https://aist.repo.nii.ac.jp/records/2001787
https://aist.repo.nii.ac.jp/records/200178741e0fa25-4cee-4f44-89a6-a31e24b97d4b
| Item type | Research Data (v9)(1) | |||||||||||
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| PubDate | 2014-01-01 | |||||||||||
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| Title | Dynamic Design of Cross Linked Soft Material driven by Iron Complex | |||||||||||
| Language | ja | |||||||||||
| Description of data | ||||||||||||
| Description Type | Abstract | |||||||||||
| Description | One dissipative structure being a key feature of space-time self-assembly of nonequiliburium systems, which exhibits temporal and spatiotemporal oscillation is known to be chemically generated by the famous Belousov-Zhabotinsky (BZ) reaction. The BZ reaction is known as an oscillating reaction with a rhythmic oscillation based the redox potential of metal catalysts such as rhutenium tris(2,2’-bipyridine) (Ru(bpy)3) and iron tris-phenanthroline complexes, namely ferroin. That is usually because iron tris(2,2’-bipyridine) is unstable in the BZ reaction. It is convenient to harness cheap metals as a catalyst of the BZ reaction toward industrial applications, however, self-oscillating cross-linked gel systems undergoing swelling-deswelling oscillation are catalyzed only by using the expensive Ru(bpy)3 complex, so far. We have demonstrated a self-oscillating cross-linked gel, which, swells/deswells periodically with the redox oscillation of ferroin for the first time. This novel self-oscillating gel exhibits 7% change in the gel length and continues the swelling-deswelling oscillation for 6 hours. | |||||||||||
| Language | ja | |||||||||||
| Author (Creator) name |
向井 理
× 向井 理
× 都 貞喜
× 有村 隆志
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| Access Rights | ||||||||||||
| Access Rights | open access | |||||||||||
| Access Rights URI | http://purl.org/coar/access_right/c_abf2 | |||||||||||
| APC | ||||||||||||
| APC | Not required | |||||||||||
| Rights Holder | ||||||||||||
| Right Holder Name | 向井 理 | |||||||||||
| Language | ja | |||||||||||
| Publisher | ||||||||||||
| Publisher | 電子情報通信学会 | |||||||||||
| Language | ja | |||||||||||
| Date | ||||||||||||
| Date | 2014-01-01 | |||||||||||
| Date Type | Issued | |||||||||||
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| Language | jpn | |||||||||||
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| Resource Type Identifier | http://purl.org/coar/resource_type/c_6501 | |||||||||||
| Resource Type | journal article | |||||||||||
| Relation | ||||||||||||
| Relation Type | isVersionOf | |||||||||||
| Identifier Type | URI | |||||||||||
| Related Identifier | http://jglobal.jst.go.jp/en/public/201502221892260767 | |||||||||||
| Language | ja | |||||||||||
| Related Title | 関連 URI | |||||||||||
| Source Title | ||||||||||||
| Source Title | 電子情報通信学会技術研究う報告 | |||||||||||
| Language | ja | |||||||||||
| Volume Number | ||||||||||||
| Volume | 114 | |||||||||||
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| Issue | 341 | |||||||||||
| Page Start | ||||||||||||
| Start Page | 11 | |||||||||||
| Page End | ||||||||||||
| End Page | 15 | |||||||||||
